Synthesis and characterization of ZnO nanoparticles using the duwet (Syzygium cumini) leaf extract as a bioreductor

Authors

  • Emmy Yuanita Department of Chemistry, University of Mataram, Mataram, Indonesia
  • Ainni Rohmana Department of Chemistry, University of Mataram, Mataram, Indonesia
  • Maria Ulfa Department of Chemistry, Faculty of Science, University of Mataram
  • Baiq Nila Sari Ningsih Department of Chemistry, University of Mataram, Mataram, Indonesia
  • Sudirman Sudirman Department of Chemistry, Faculty of Science, University of Mataram
  • Ni Komang Tri Dharmayani Department of Chemistry, Faculty of Science, University of Mataram
  • Ima Arum Lestarini Department of Medical, University of Mataram, Mataram, Indonesia
  • Baiq Desy Ratnasari Department of Chemistry and biochemistry, University of North Carolina, Greensboro, USA

DOI:

https://doi.org/10.29303/aca.v8i1.175

Keywords:

ZnO nanoparticles, duwet leaf, bioreductor, zink acetate dihydrat

Abstract

Synthesis of ZnO nanoparticles was carried out using a green synthesis method that utilizes plants as bioreductors. Secondary metabolites contained in plants can act as bioreductors in the metal oxide reduction process and capping agents in the production of ZnO nanoparticles. In this study, the characterization of ZnO nanoparticles was carried out using duwet (Syzygium cumini) leaf extract. The Synthesis was carried out by varying the composition of zinc acetate dihydrate solution and duvet leaf extract in the 1:1, 1:2, 1:3, and 1:4 ratios, as well as pH 7, 8, 9, and 10. The resulting ZnO nanoparticles were then characterized using UV-Vis spectrophotometry to determine the optimal conditions, a Particle Size Analyzer (PSA) to determine the particle size and X-ray diffraction (XRD) to determine the purity of the resulting nanoparticles by looking at the 2θ peak formed. Optimal conditions for synthesizing ZnO nanoparticles were obtained with a maximum wavelength (λmax) of 369 nm at a ratio of 1:2 and pH 8. The particle size distribution analysis results from PSA showed an average size of 19.52 nm, with a Poly Dispersity Index (PDI) value of 0.2491. The results of the analysis using XRD showed that the synthesized nanoparticles showed typical peaks for ZnO with 2θ values of 31.7680º, 34.3699º, and 36.2281º, which indicated that the Synthesis of nanoparticles had successfully produced pure ZnO nanoparticles.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

Rambaran T. & Schirhagl R. (2022). Nanotechnology from lab to industry - a look at current trends. Royal Society of Chemistry, 4, 3664-3675.

Malik S., Muhammad K., and Waheed Y. (2023). Nanotechnology: a revolution in modern industry. Molecules, 28(661), 1-26.

Elzein B. (2024). Nano revolution: “tiny tech, big impact: how nanotechnology is driving sdgs progress. Heliyon, 10(10), 1-26.

Haleema X., Munir M. U., Phan D. N., and Khan M. Q. (2022). Recycling of nanomaterials by solvent evaporation and extraction techniques. Nanomaterials Recycling, 10, 209–222.

Khan I., Saeed K., and Khan I. (2019). Nanoparticles: properties, applications and toxicities. Arabian Journal of Chemistry, 12(7), 908–931.

Mekuye B. & Abera B. (2023). Nanomaterials: an overview of synthesis, classification, characterization, and applications. Nano Select, 4(8), 486–501.

Perna, Anubhav D., & Gupta R. (2021). Nanoparticles: an overview. Drugs and Cell Therapies in Haematology, 10(1), 1487–1897.

Shinde M. U. et al. (2022). Nanomaterials: a potential hope for life sciences from bench to bedside. Journal of Nanomaterials, 1-13.

Zhou X. Q. et al. (2023). Zinc oxide nanoparticles: synthesis, characterization, modification, and applications in food and agriculture. Processes, 11, 1-23.

Mandal A. K. et al. (2022). Current research on zinc oxide nanoparticles: synthesis, characterization, and biomedical applications. Nanomaterials, 12(17), 1-31.

Preethi S. et al. (2020) Synthesis and characterization of chitosan/zinc oxide nanocomposite for antibacterial activity onto cotton fabrics and dye degradation applications. International Journal Biological Macromolecules, 164, 2779–2787.

Al-darwesh M. Y., Ibrahim S. S., & Mohammed M. A. (2024). A review on plant extract mediated green synthesis of zinc oxide nanoparticles and their biomedical applications. Results in Chemistry, 7, 1-18.

Islam F. et al. (2022). Exploring the journey of zinc oxide nanoparticles (ZnO-NPs) toward biomedical applications. Materials, 15, 1-31.

Lakshmipriya T. & Gopinath S. C. B. (2020). Introduction to nanoparticles and analytical devices. Materials, 1–29.

Osman A. I. et al. (2024). Synthesis of green nanoparticles for energy, biomedical, environmental, agricultural, and food applications: A review. Enviromental Chemistry Letters, 22, 841-887.

Agarwal H., Kumar S. V., & Rajeshkumar S. (2017). A review on green synthesis of zinc oxide nanoparticles - an eco-friendly approach. Resource-Efficient Technologies, 3(4), 406–413.

Eddy D. R. et al. (2024). A review of recent developments in green synthesis of TiO2 nanoparticles using plant extract: synthesis, characterization and photocatalytic activity. Inorganic Chemistry Communications, 165, 112531.

Faisal S. et al. (2021). Green synthesis of zinc oxide (ZnO) nanoparticles using aqueous fruit extracts of myristica fragrans: their characterizations and biological and environmental applications. ACS Omega, 6(14), 9709–9722.

Alqarni L. S., Alghamdi M. D., Alshahrani A. A., & Nassar A. M. (2022). Green nanotechnology: recent research on bioresource-based nanoparticle synthesis and applications. Journal of Chemistry, 1-31.

Kazemi S. et al. (2023). Recent advances in green synthesized nanoparticles: from production to application. Materials Today Sustainability, 24, 100500.

Samuel M. S. et al. (2022). A review on green synthesis of nanoparticles and their diverse biomedical and environmental applications. Catalysts, 12, 1-24.

Abdelbaky A. S., Mohamed A., Sharaky M., Mohamed N. A., & Diab Y. M. (2023). Green approach for the synthesis of ZnO nanoparticles using Cymbopogon citratus aqueous leaf extract: characterization and evaluation of their biological activities. Chemical and Biological Technologies in Agriculture, 10(63), 1-23.

Fatoni A., Afrizal M. A., Rasyad A. A., & Hidayat N. (2021). ZnO Nanoparticles and its interaction with chitosan : profile spectra and their activity against bacterial. Jurnal Kimia dan Pendidikan Kimia, 6(2), 216- 227.

Umamaheswari A., Prabu S. L., John S. A., & Puratchikody A. (2021). Green synthesis of zinc oxide nanoparticles using leaf extracts of Raphanus sativus var. Longipinnatus and evaluation of their anticancer property in A549 cell lines. Biotechnology Reports, 29, 1-9.

Firisa S. G., Muleta G. G., and A. A. Yimer. (2022). Synthesis of nickel oxide nanoparticles and copper-doped nickel oxide nanocomposites using phytolacca dodecandra L’herit leaf extract and evaluation of its antioxidant and photocatalytic activities. ACS Omega, 7(49), 44720–44732.

Rajkumar G., Panambara P., & Sanmugarajah V. (2022). Comparative analysis of qualitative and quantitative phytochemical evaluation of selected leaves of medicinal plants in jaffna, sri lanka. Borneo Journal of Pharmacy, 5(2), 93–103.

Priyanka S., Dixit S., & Sahoo S. (2017). Phytochemical and biochemical characterizations from leaf extracts from Azadirachta indica: an important medicinal plant. Biochemistry & Analytical Biochemistry, 17(3), 6961–6979.

Sa’adah S. M., Putri F. R., Ibtisam A. A., & Arrohmah R. S. (2023). Phytochemical analysis of secondary metabolite compounds of pandanwangi leaf extract (Pandanus amaryllifolius). Journal of Natural Sciences and Mathematics Research, 9(2), 135–142.

Laxmi & Begum T. (2022). Phytochemical analysis of leaf extract of the medicinal plants. Journal of Medicinal Plants Studies, 10(6), 34–36.

Ahmed M. et al. (2019). Phytochemical screening, total phenolic and flavonoids contents and antioxidant activities of citrullus colocynthis L. and Cannabis Sativa L. Applied Ecology Environmetal Research, 17(3), 6961–6979.

Rhamdiyah F. K. and Maharani D. K. (2022). Biosynthesis of ZnO nanoparticles from aqueous extract of Moringa Oleifera L.: its application as antibacterial and photocatalyst. Indonesian Journal of Chemical Science, 11(2), 92–102.

Setiani F. and Suyatno. (2024) “Synthesis and characterization of copper nanoparticles with bioreductor carica dieng (carica pubescens) seed extract. Journal Pijar Mipa, 19, 151–155.

Sutoyo, S., Tukiran, & Khotijah, S. (2021). Antioxydant activity of the silver nanoparticles (AgNPs) synthesized using Nephrolepisradicans extract as bioreductor. Journal of Physics: Conference Series, 1747(1).

Wang Q., Mei S., Manivel P., Ma H., & Chen X. (2022). Zinc oxide nanoparticles synthesized using coffee leaf extract assisted with ultrasound as nanocarriers for mangiferin. Current Research Food Science, 5, 868–877.

Oktavia, F. D. & Sutoyo, S. (2021). Skrining fitokimia, kandungan flavonoid total, dan aktivitas antioksidan ekstrak etanol tumbuhan Selaginella doederleinii. Jurnal Kimia Riset, 6(2), 141–153.

Sutoyo, S., Amaria, A., Sanjaya, I.G.M., Hidayah, R., Sari, D.P., Dwitarini, N., Oktavia, F.D., Fadzlillah, N.A. (2022). Synthesis of nanoherbal from ethanol extract of indonesian fern Selaginella plana and antibacterial activity assay, Tropical Journal of Natural Product Research, 6(1), 44-49.

Synthesis and characterization of ZnO nanoparticles using the duwet (Syzygium cumini) leaf extract

Downloads

Published

2025-05-31

How to Cite

Yuanita, E., Rohmana, A. ., Ulfa, M. ., Ningsih, B. N. S. ., Sudirman, S., Dharmayani, N. K. T. ., Lestarini, I. A., & Ratnasari, B. D. . (2025). Synthesis and characterization of ZnO nanoparticles using the duwet (Syzygium cumini) leaf extract as a bioreductor. Acta Chimica Asiana, 8(1), 541–547. https://doi.org/10.29303/aca.v8i1.175

Issue

Section

Articles

Most read articles by the same author(s)