Synthesis of nanochitosan from oyster pearl shell (Pinctada maxima) as renewable energy candidate
Penulis
Susi Rahayu , Geby Alawiyah , Dian W. Kurniawidi , Teguh Ardianto , Arif , Siti Alaa , Syamsuddin SyamsuddinDOI:
10.29303/aca.v7i2.205Diterbitkan:
2024-10-31Terbitan:
Vol 7 No 2 (2024)Kata Kunci:
Degree of deacetylation, electrolyte polymer, zet potentiaArticles
Unduhan
Cara Mengutip
Unduhan
Metrik
Abstrak
The increase in energy needs must be balanced by environmentally friendly technological innovations. Chitosan polymer is one of the technological innovations of energy materials that are being developed by many developed countries. This research aimed to identify the potential of oyster pearl shell waste as a source of electrolyte polymers. The study was conducted experimentally by synthesizing chitosan nanoparticles from chitosan using the ionic gelation method. Chitosan is obtained through the isolation method from Pinctada maxima oyster pearl shell waste. The isolation method is carried out by three processes: deproteination, demineralization, and deacetylation. Several characterizations were carried out to analyze the material from the synthesis, including a proximate test, FTIR analysis, and PSA analysis. Isolated chitosan was identified to have a deacetylation degree that reached 88.63% with the formation of OH and NH2 functional groups. In general, the proximate tets data has shown that the obtained chitosan already meets the Indonesian standard SNI 7949:2013. PSA analysis resulted in differences in size distribution, PDI, and zeta potential between chitosan and chitosan nanoparticles. The results were obtained by the average distribution of chitosan particle size of 52.043 μm and chitosan nanoparticle size of 2.3365 μm—the analysis of the potential zeta of chitosan -3.9 mV and chitosan nanoparticle -21,6 mV. Thus, changes in the size of the chitosan material affect its potential PDI and zeta values. The change of these two values is a good indicator of the initial data and the potential of the material as an energy material. Therefore, chitosan polymer is an electrolyte material that can be used as a candidate for environmentally friendly renewable energy materials
Referensi
Verma, R., Singhbabu, Y. N., Didwal, P. N., Nguyen, A. G., Kim, J., & Park, C. J. (2020). Biowaste orange peel‐derived mesoporous carbon as a cost‐effective anode material with ultra‐stable cyclability for potassium‐ion batteries. Batteries & Supercaps, 3(10), 1099-1111.
S. T. Gonggo, A. Wahid, M. Diah, and R. Lateene, “Effects of Kaolin on Chitosan-Polyvinyl Alcohol-Lithium Blend Membrane as Electrolytes Membrane For Lithium Ion Battery A,” J. Akad. Kim., vol. 6, no. 1, pp. 55–64, 2017.
Wan, Y., Creber, K. A., Peppley, B., & Bui, V. T. (2006). Chitosan-based solid electrolyte composite membranes: I. Preparation and characterization. Journal of Membrane Science, 280(1-2), 666-674. .
B. Aziz, S., Hamsan, M. H., M. Nofal, M., San, S., Abdulwahid, R. T., Raza Saeed, S., ... & Al-Zangana, S. (2020). From cellulose, shrimp and crab shells to energy storage EDLC cells: the study of structural and electrochemical properties of proton conducting chitosan-based biopolymer blend electrolytes. Polymers, 12(7), 1526.
M. I. Bin Zamli, M. H. M. Akmal, F. B. Ahmad, and F. Hisham, “Piezoelectric Performance of Microbial Chitosan Thin Film Derived from Aspergillus oryzae,” Int. J. Renew. Energy Dev., vol. 11, no. 4, pp. 1157–1164, 2022, doi: 10.14710/ijred.2022.47260.
D. Handayani, S. Alaa, D. W. Kurniawidi, and S. Rahayu, “Pengolahan Limbah Cangkang Kerang Mutiara (Pinctada Maxima) Sebagai Adsorben Logam Berat Fe,” J. Pertamb. dan Ligkungan, vol. 3, no. 2, pp. 10–15, 2022.
Nurlaili, S. Alaa, and S. Rahayu, “Modifikasi Teknik Isolasi Biopolimer Kitosan Dari Cangkang Kerang Mutiara (Pinctada Maxima) Sebagai Adsorben Zat Warna Metilen Blue,” ORBITA J. Kajian, Inov. dan Apl. Pendidik. Fis., vol. 8, no. 2, pp. 268–273, 2022, doi: 10.31764/orbita.v8i2.11462.
S. E. Nurmaulida et al., “Fabrication of Chitosan Biopolymer from Pearl Oyster Shells (Pinctada maxima) for Medical Applications,” Indones. Phys. Rev., vol. 6, no. 2, pp. 240–249, 2023.
Shaari, N., & Kamarudin, S. K. (2015). Chitosan and alginate types of bio-membrane in fuel cell application: An overview. Journal of Power Sources, 289, 71-80.
L. Handayani, F. Syahputra, and Y. Astuti, “Utilization and Characterization of Oyster Shell as Chitosan and Nanochitosan,” J. Kim. Sains dan Apl., vol. 21, no. 4, pp. 224–231, 2018, doi: 10.14710/jksa.21.4.224-231.
M. E. A. Ali, M. M. S. Aboelfadl, A. M. Selim, H. F. Khalil, and G. M. Elkady, “Chitosan Nanoparticles Extracted From Shrimp Shells, Application for Removal of Fe(II) and Mn(II) from Aqueous Phases,” Sep. Sci. Technol., vol. 53, no. 18, pp. 2870–2881, 2018, doi: 10.1080/01496395.2018.1489845.
O. Sjofjan, M. H. Natsir, and S. Chuzaemi, Ilmu Nutrisi Ternak Dasar. Malang: Universitas Brawijaya Press, 2019. [Online]. Available: https://books.google.co.id/books?id=PQDcDwAAQBAJ
R. K. Goyal, Nanomaterials and Nanocomposites : Synthesis, Properties, Characterization Techniques and Applications. New York: CRC Press, 2018. doi: 10.1201/9781315153285.
S. Horiba, A Guidebook To Particle Size Analysis. 2010.
R. Napsah and I. Wahyuningsih, “Preparasi Nanopartikel Kitosan-TPP/ Ekstrak Etanol Daging Buah Mahkota Dewa (Phalaeriamacrocarpa(Scheff) Boerl) dengan Metode Gelasi Ionik,” J. Farm. Sains dan Komunitas, vol. 11, no. 1, pp. 7–12, 2014.
D. Wiliana, S. Alaa, and T. Ardianto, “Fabrikasi Membran Biopolimer Kitosan Dari Cangkang Kerang Mutiara (Pinctada maxima) Sebagai Adsorben Metilen Biru,” J. Kim. Pendidik. Kim., vol. 4, no. 62, pp. 48–57, 2022, doi: 10.20414/spin.v4i1.5371.
A. Setiabudi, R. Hardian, and A. Muzakir, Karakterisasi Material: Prinsip dan Aplikasinya dalam Penelitian Kimia, vol. 1. 2012.
M. Wu et al., “A Sustainable Chitosan-Zinc Electrolyte for High-Rate Zinc-Metal Batteries,” Matter, vol. 5, no. 10, pp. 3402–3416, 2022, doi: 10.1016/j.matt.2022.07.015.
Mursida, Tasir, and Sahriawati, “Efektifitas Larutan Alkali pada Proses Deasetilasi dari Berbagai Bahan Baku Kitosan,” Jphpi, vol. 21, no. 2, pp. 356–366, 2018.
A. Pebiansyah and A. Yuliana, “Aktivitas Antibakteri Kitosan dari Cangkang Lobster Air Tawar (Cherax quadricarinatus) terhadap Staphylococcus aureus,” in Seminar Nasional Diseminasi Penelitian Program Studi S1 Farmasi 2021 STIKes BTH Tasikmlaya Tema: “Kontribusi Riset Farmasi di Masa Pandemi,” Tasikmalaya: Jakad Media Publishing, 2021, pp. 70–76. [Online]. Available: https://books.google.co.id/books?id=-R9YEAAAQBAJ
BSN, Kitosan-Syarat Mutu dan Pengolahan SNI No. 7949. Jakarta: Dewan Standardisasi Nasional., 2013.
S. Gärtner et al., “Turning Seashell Waste into Electrically Conductive Particles,” Int. J. Mol. Sci., vol. 23, no. 13, pp. 1–12, 2022, doi: 10.3390/ijms23137256.
M. Dembek, S. Bocian, and B. Buszewski, “Solvent Influence on Zeta Potential of Stationary Phase—Mobile Phase Interface,” Molecules, vol. 27, no. 3, pp. 1–11, 2022, doi: 10.3390/molecules27030968.
A. G. Samudra, N. Ramadhani, G. Lestari, and B. H. Nugroho, “Formulasi Nanopartikel Kitosan Ekstrak Metanol Alga Laut Coklat (Sargassum hystrix ) dengan Metode Gelasi Ionik,” J. Ilm. Manuntung, vol. 7, no. 1, pp. 92–99, 2021.
Lisensi
Hak Cipta (c) 2024 Susi Rahayu, Geby Alawiyah, Dian W. Kurniawidi, Teguh Ardianto, Arif Budianto, Siti Alaa, Syamsuddin Syamsuddin
Artikel ini berlisensiCreative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Authors who publish with ACA: Acta Chimica Asiana agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License. This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in ACA: Acta Chimica Asiana.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).